Walter Brattain began working at Bell Labs in 1929. Mervin Kelly was
a researcher at Bell Labs who became its director of research in
1936. He envisioned telephone switches being electronic rather
than mechanical. William Shockley was Kelly’s first hire after a
hiring freeze was lifted in 1936. Kelly hired Shockley for the
latter’s knowledge of quantum mechanics. Shockley took Kelly’s
vision as a guiding light. For the next several years, Bell Labs grew
its research staff with specialists in quantum mechanics. In 1937
Clinton Davisson of Bell Labs won the Nobel Prize for his experiments
that electrons behaved like waves.
Brattain and Joseph Becker studied the papers of Walter Shottky and
Nevill Mott (neither at Bell Labs). The papers said that whenever a
metal and a semiconductor come into contact, a double layer of charge
crops up – positive on one side and negative on the other –
because of the difference in work functions of the two materials.
This leads to a kind of “hill” that electrons must surmount if
they are to cruise from one side to the other. “Because this hill
is asymmetric, with a steep cliff on the metal side and a shallow
slope on the other, electrons move far more readily from
semiconductor to metal than in the opposite direction." This finally
provided a satisfactory explanation of rectification, which had
mystified scientists for 65 years. Shockley, Brattain, and Becker
attempted fabricating devices to make use of this effect. Not only
was progress slow, it was interrupted with work on topics like radar,
submarine detection, mines, and torpedoes due to World War II.
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